You are in the College of Science and Liberal ArtsCollege of Science and Liberal Arts

Department of Chemistry and Environmental Science

Krasnoperov, Lev N.

Contact Info
Title: Professor, Chemistry
Email: lev.n.krasnoperov@njit.edu
Office: 358 Tiernan
Phone: 973-596-3592
Dept: Chemistry and Environmental Science
Webpage:

Academic Interests: chemical kinetics, thermodynamics

About Me



Education

  • Doctor of Sciences in Physics and Mathematics (Chemical Physics)
  • Institute of Chemical Physics, Moscow, 1991
  • PhD (Chemical Physics), Institute of Chemical Kinetics and Combustion, Novosibirsk, 1979
  • Diploma, Physics and Applied Mathematics, Novosibirsk University, Novosibirsk, 1972

Courses I Teach

RESEARCH & INDEP STUDY
MASTERS THESIS
DOCT DISSERTATION & RES
DOCT DISSERTATION & RES
DOCT DISSERTATION & RES
DOCT DISSERTATION & RES
PHYSICAL CHEM FOR CHEM ENGRS
RESEARCH & INDEP STUDY I
GRADUATE CO-OP WORK EXPER I
GRADUATE CO-OP WORK EXPER III
INDEPENDENT STUDY I
INDEPENDENT STUDY II
MASTERS PROJECT
MASTERS THESIS
MASTERS THESIS
DOCTORAL DISSERTATION
DOCTORAL DISSERTATION
DOCTORAL DISSERTATION
DOCTORAL DISSERTATION
DOCTORAL DISSERTATION
DOCTORAL DISSERTATION
DOCT DISSERTATION & RES

Courses Taught

CHEM 231´01S         PhysicalChemistry 1

CHEM 235´00F         Physical Chemistry 2

CHEM 235A:            Physical Chemistry Laboratory: Kinetics of Ozone Formation by Laser Photolysis -Transient UV Spectroscopy

OPSE 601                 Abstract CS101E                     Experiment5                                   Experiment 6 CHEM 534 - Chemical Kinetics and Thermodynamics CHEM 702 - Advanced Chemical Kinetics (Lecture) CHEM 658 - Advanced Physical Chemistry - Quantum Chemistry (Lecture) CHEM 335 - Physical Chemistry 2 (Lecture) CHEM 235 - Physical Chemistry 2 (Lecture) CHEM 231 - Physical Chemistry 1 (Lecture)- syllabus CHEM 301 - Chemical Technology (Laboratory)

At the Catholic University of America, Washington, D.C.:

CHEM 530 - Chemical Thermodynamics (Lecture) Unimolecular Reactions (Lecture)

At Novosibirsk University: Chemical Kinetics (graduate course, lecture) General Physics -  4 semesters´ undergraduate course:     Mechanics,     Electricity and Magnetism,     Quantum mechanics,     Statistical Thermodynamics. Chemical Kinetics Molecular Structure and Spectroscopy (graduate course, lecture) Molecular structure and spectroscopy (undergraduate course, lecture) Mass Spectrometry (laboratory) Kinetic Spectroscopy of Laser Magnetic Resonance (laboratory) Computer Classes in Physical Chemistry (laboratory)

Participation in the Development of New Courses:

OPSE 601 OPTICAL SCIENCE AND ENGINEERING (NJIT) 09/01/98-12/15/98

The course targets applications of optical  methods in a varietyof fields, such as chemistry, chemical engineering, telecommunications,electrical engineering, etc.  

CS101E INTRODUCTORY OPTICAL SCIENCE (NJIT) 09/01/98-12/15/98

The main objective is to familiarize students from different disciplines with the optical techniques, applications and capabilities.

CHEM 235A NEW PHYSICAL CHEMISTRY LAB (NJIT) 10/01/98-12/15/98

"Introduction of Laser Photolysis – Transient Spectroscopy Experiments in a Physical Chemistry Lab" – a new physical chemistry lab developed andbuilt under NSF Grant DUE-97 51686. The lab objectives are to introduce students to elementary chemicalkinetics, ozone formation and the modern techniques in kinetic measurements.

CHEM 702 ADVANCED CHEMICAL KINETICS (NJIT) 1/9/95-30/12/95

Graduate course focusing on the role of media chemical reactions, such as pressure fall-off in gas phase unimolecular reactions and solvent properties in liquid phase reactions, and the current chemical reaction rate theories.  

UNIMOLECULAR REACTIONS 1/9/92-30/12/92 (CUA, Washington, D.C.)

Graduate course focusing on modern theories and applications of unimolecular reactions.  

CHEMICAL KINETICS 1/9/90-30/12/90 ( Novosibirsk University):1/9/86-30/12/89

Graduate course focusing on elementary and complex chemical reactionsin the gas and liquid phases.

KINETIC SPECTROSCOPY OF LASER MAGNETIC RESONANCE (Novosibirsk University) 1/1/84-30/5/85

An undergraduate laboratory focusing on application of a modern technique of Time Resolved Laser Magnetic Resonance for measurements of rates ofelementary chemical reactions of atoms and free radicals.  

COMPUTER CLASSES in Physical Chemistry (Novosibirsk University) 9/1/83-12/30/85

An undergraduate laboratory focusing on using computers for solution of  physical chemistry problems.


Research Interests

  • Chemical kinetics and thermodynamics of gas phase reactions. Thermodynamics of free radicals and strengths of chemical bonds.
  • Kinetics of particle nucleation and growth.
  • Reactions in non-thermal plasmas.
  • Supercritical fluids as process media.
  • Reactions, film deposition and nanoparticle formation from supercritical solutions

Published Refereed Journal Papers

 (1) Wirpsza, L.; Krasnoperov, L.; Mustaev, A.: New quinolone-based thiol-reactive lanthanide luminescent probes. Journal of Photochemistry and Photobiology, A: Chemistry 2013, 253, 30-37.

(2) Sangwan, M.; Krasnoperov Lev, N.: Kinetics of the Gas Phase Reaction CH3 + HO2. The Journal of Physical Chemistry A, Just Accepted Manuscript. DOI: 10.1021/ jp4000889. Publication Date (Web): March 4, 2013 2013.

(3) Rissanen, M. P.; Amedro, D.; Krasnoperov, L.; Marshall, P.; Timonen, R. S.: Gas Phase Kinetics and Equilibrium of Allyl Radical Reactions with NO and NO2. Journal of Physical Chemistry A 2013, 117, 793-805.

(4) Pillai, S.; Krasnoperov, L.; Mustaev, A.: Simple no-chromatography procedure for amine-reactive Eu3+ luminescent chelates optimal for bioconjugation. Journal of Photochemistry and Photobiology, A: Chemistry 2013, 255, 16-23.

(5) Wirpsza, L.; Pillai, S.; Batish, M.; Marras, S.; Krasnoperov, L.; Mustaev, A.: Highly bright avidin-based affinity probes carrying multiple lanthanide chelates. Journal of Photochemistry and Photobiology, B: Biology 2012, 116, 22-29.

(6) Sangwan, M.; Krasnoperov, L. N.: Disproportionation Channel of Self-Reaction of Hydroxyl Radical, OH + OH → H2O + O, Studied by Time-Resolved Oxygen Atom Trapping. Journal of Physical Chemistry A 2012, 116, 11817-11822.

(7) Sangwan, M.; Chesnokov, E. N.; Krasnoperov, L. N.: Reaction OH + OH Studied over the 298-834 K Temperature and 1 - 100 bar Pressure Ranges. Journal of Physical Chemistry A 2012, 116, 6282-6294.

(8) Sangwan, M.; Chesnokov, E. N.; Krasnoperov, L. N.: Reaction CH3 + OH Studied over the 294-714 K Temperature and 1-100 bar Pressure Ranges. Journal of Physical Chemistry A 2012, 116, 8661-8670.

(9) Pillai, S.; Wirpsza, L.; Kozlov, M.; Marras, S. A. E.; Krasnoperov, L. N.; Mustaev, A.: New cross-linking quinoline- and quinolone-based luminescent lanthanide probes for sensitive labeling. Proceedings of SPIE 2012, 8233, 82331C/1-82331C/12.

(10) Pillai, S.; Kozlov, M.; Marras, S. A. E.; Krasnoperov, L. N.; Mustaev, A.: New Cross-Linking Quinoline and Quinolone Derivatives for Sensitive Fluorescent Labeling. Journal of Fluorescence 2012, 22, 1021-1032.

(11) Pillai, S.; Kozlov, M.; Marras, S. A. E.; Krasnoperov, L.; Mustaev, A.: Synthesis and Characterization of New Cross-linkable Quinolone and Quinoline-based Luminescent Lanthanide Chelates. J. Progress in Nanotechnology and Nano Materials 2012, 1, 18-24.

(12) Kuznetsov, N. A.; Vorobjev, Y. N.; Krasnoperov, L. N.; Fedorova, O. S.: Thermodynamics of the multi-stage DNA lesion recognition and repair by formamidopyrimidine- DNA glycosylase using pyrrolocytosine fluorescence-stopped-flow pre-steady-state kinetics. Nucleic Acids Research 2012, 40, 7384-7392.

(13) Stepanov, V.; Anglade, V.; Balas Hummers, W. A.; Bezmelnitsyn, A. V.; Krasnoperov, L. N.: Production and Sensitivity Evaluation of Nanocrystalline RDX-based Explosive Compositions. Propellants, Explosives, Pyrotechnics 2011, 36, 240-246.

(14) Mustaev, A.; Kozlov, M.; Marras, S.; Krasnoperov, L.; Wirpsza, L.; Pillai, S.: Fluorophore chelated lanthanide luminescent probes with improved quantum efficiency. (University of Medicine and Dentistry of New Jersey, USA; New Jersey Institute of Technology). Application: WO WO, 2011; pp 103pp.

(15) Krasnoperov, L. N.: Branching Ratios in the Hydroxyl Reaction with Propene. Journal of Physical Chemistry A 2011, 115, 2498-2508.

(16) Krasnoperov, L. N.; Marras, S. A. E.; Kozlov, M.; Wirpsza, L.; Mustaev, A.: Luminescent probes for ultrasensitive detection of nucleic acids. Bioconjugate Chemistry 2010, 21, 319-327.

(17) Chernov, A. A.; Korobeinichev, O. P.; Modenese, C.; Krishtopa, L. G.; Krasnoperov, L. N.: Kinetics, products, and mechanism of ethane destruction in corona discharge: Experiments and simulation. Kinetics and Catalysis 2010, 51, 327-336.

(18) Stepanov, V.; Anglade, V.; Balas, W.; Bezmelnitsyn, A.; Krasnoperov, L. N.: Processing and characterization of nanocrystalline RDX. International Annual Conference of ICT 2008, 39th, p54/1-p54/15.

(19) Eskola, A. J.; Timonen, R. S.; Marshall, P.; Chesnokov, E. N.; Krasnoperov, L. N.: Rate Constants and Hydrogen Isotope Substitution Effects in the CH3 + HCl and CH3 + Cl2 Reactions. Journal of Physical Chemistry A 2008, 112, 7391-7401.

(20) Matsunaga, T.; Chernyshev, A. V.; Chesnokov, E. N.; Krasnoperov, L. N.: In situ optical monitoring of RDX nanoparticles formation during rapid expansion of supercritical CO2 solutions. Physical Chemistry Chemical Physics 2007, 9, 5249-5259.

(21) Chesnokov, E. N.; Krasnoperov, L. N.: Complete thermodynamically consistent kinetic model of particle nucleation and growth: numerical study of the applicability of the classical theory of homogeneous nucleation. Journal of Chemical Physics 2007, 126, 144504/1- 144504/15.

(22) Stepanov, V.; Anglade, V.; Bezmelnitsyn, A.; Krasnoperov, L. N.: Production and characterization of nanocrystalline explosive RDX. AIChE Annual Meeting, Conference Proceedings, San Francisco, CA, United States, Nov. 12-17, 2006 2006, 399e/1-399e/6.

(23) Krasnoperov, L. N.; Peng, J.; Marshall, P.: Modified Transition State Theory and Negative Apparent Activation Energies of Simple Metathesis Reactions: Application to the Reaction CH3 + HBr → CH4 + Br. Journal of Physical Chemistry A 2006, 110, 3110-3120.

(24) Krasnoperov, L. N.: Role of formyl radical (HCO) in hydrocarbon flames. Khimicheskaya Fizika 2006, 25, 13-17.

(25) Gao, Y.; Alecu, I. M.; Hsieh, P. C.; Morgan, B. P.; Marshall, P.; Krasnoperov, L. N.: Thermochemistry Is Not a Lower Bound to the Activation Energy of Endothermic Reactions: A Kinetic Study of the Gas-Phase Reaction of Atomic Chlorine with Ammonia. Journal of Physical Chemistry A 2006, 110, 6844-6850.

(26) Stepanov, V.; Samuels, P.; Elkina, I. B.; Zhang, X.; Lavrik, N. L.; Krasnoperov, L. N.: Recrystallization of RDX by rapid expansion of supercritical solutions (RESS). International Annual Conference of ICT 2005, 36th, 189/1-189/8.

(27) Stepanov, V.; Krasnoperov, L. N.; Elkina, I. B.; Zhang, X.: Production of nanocrystalline RDX by Rapid Expansion of Supercritical Solutions. Propellants, Explosives, Pyrotechnics 2005, 30, 178-183.

(28) Krasnoperov, L. N.; Chesnokov, E. N.; Stark, H.; Ravishankara, A. R.: Elementary reactions of formyl (HCO) radical studied by laser photolysis-transient absorption spectroscopy. Proceedings of the Combustion Institute 2005, 30, 935-943.

(29) Krasnoperov, L. N.: The thermal unimolecular decomposition of HCO: effect of state specific rate constants on the thermal rate constant. Comment. Physical Chemistry Chemical Physics 2005, 7, 2074-2076. (30) Johnson, D.; Raoult, S.; Lesclaux, R.; Krasnoperov, L. N.: UV absorption spectra of methyl-substituted hydroxy-cyclohexadienyl radicals in the gas phase. Journal of Photochemistry and Photobiology, A: Chemistry 2005, 176, 98-106.

(31) Krasnoperov, L. N.; Michael, J. V.: Shock Tube Studies Using a Novel Multipass Absorption Cell: Rate Constant Results For OH + H2 and OH + C2H6. Journal of Physical Chemistry A 2004, 108, 5643-5648.

(32) Krasnoperov, L. N.; Michael, J. V.: High-Temperature Shock Tube Studies Using Multipass Absorption: Rate Constant Results for OH + CH3, OH + CH2, and the Dissociation of CH3OH. Journal of Physical Chemistry A 2004, 108, 8317-8323.

(33) Krasnoperov, L. N.; Chesnokov, E. N.; Stark, H.; Ravishankara, A. R.: Unimolecular Dissociation of Formyl Radical, HCO → H + CO, Studied over 1-100 Bar Pressure Range. Journal of Physical Chemistry A 2004, 108, 11526-11536.

(34) Hahn, J.; Krasnoperov, L.; Luther, K.; Troe, J.: Pressure dependence of the reaction H + O2 (+Ar) → HO2 (+Ar) in the range 1-900 bar and 300-700 K. Physical Chemistry Chemical Physics 2004, 6, 1997-1999.

(35) Grebenkin, S. Y.; Krasnoperov, L. N.: Kinetics and Thermochemistry of the Hydroxycyclohexadienyl Radical Reaction with O2: C6H6OH + O2 .dblharw. C6H6(OH)OO. Journal of Physical Chemistry A 2004, 108, 1953-1963.

(36) Krishtopa, L. G.; Krasnoperov, L. N.: Destruction of isotopically enriched nitric oxide, 15N18O, in air in corona discharge: direct observation of NOx reduction to molecular nitrogen. Journal of Advanced Oxidation Technologies 2003, 6, 30-34.

(37) Glebov, E. M.; Krishtopa, L. G.; Stepanov, V.; Krasnoperov, L. N.: Reply to Comment on "Kinetics of a Diels-Alder Reaction of Maleic Anhydride and Isoprene in Supercritical CO2". Journal of Physical Chemistry A 2003, 107, 9249.

(38) Chernov, A. A.; Krishtopa, L. G.; Korobeinichev, O. P.; Krasnoperov, L. N.: Kinetics, products and mechanism of destruction of ethane in corona discharge. Journal of Advanced Oxidation Technologies 2003, 6, 23-29.

(39) Korobeinichev, O. P.; Chernov, A. A.; Sokolov, V. V.; Krasnoperov, L. N.: Kinetics of destruction of diisopropyl methylphosphonate in corona discharge. International Journal of Chemical Kinetics 2002, 34, 331-337.

(40) Korobeinichev, O. P.; Chernov, A. A.; Sokolov, V. V.; Krasnoperov, L. N.: Degradation of organophosphorus compounds in a corona discharge. Khimicheskaya Fizika 2002, 21, 27-31.

(41) Dubtsov, S. N.; Chesnokov, E. N.; Krasnoperov, L. N.: Kinetics of the aerosol formation at 193-nm photolysis of 1,4-cyclohexadiene-NO-air mixture. Atmospheric and Oceanic Optics 2002, 15, 445-447.

(42) Glebov, E. M.; Yuan, L.; Krishtopa, L. G.; Usov, O. M.; Krasnoperov, L. N.: Coating of Metal Powders with Polymers in Supercritical Carbon Dioxide. Industrial & Engineering Chemistry Research 2001, 40, 4058-4068.

(43) Glebov, E. M.; Krishtopa, L. G.; Stepanov, V.; Krasnoperov, L. N.: Kinetics of a Diels-Alder Reaction of Maleic Anhydride and Isoprene in Supercritical CO2. Journal of Physical Chemistry A 2001, 105, 9427-9435.

(44) Baklanov, A. V.; Krasnoperov, L. N.: Oxalyl Chloride-A Clean Source of Chlorine Atoms for Kinetic Studies. Journal of Physical Chemistry A 2001, 105, 97-103. (45) Baklanov, A. V.; Krasnoperov, L. N.: UV Absorption Spectrum and Rate Constant for Self-Reaction of Silyl Radicals. Journal of Physical Chemistry A 2001, 105, 4917- 4922.

(46) Krasnoperov, L. N.; Stepanov, V.: Introduction of laser photolysis-transient spectroscopy in an undergraduate physical chemistry laboratory: kinetics of ozone formation. Journal of Chemical Education 1999, 76, 1182-1183.

(47) Krasnoperov, L. N.; Mehta, K.: Kinetic Study of CH3 + HBr and CH3 + Br Reactions by Laser Photolysis-Transient Absorption over 1-100 Bar Pressure Range. Journal of Physical Chemistry A 1999, 103, 8008-8020.

(48) Krasnoperov, L. N.; Chesnokov, E. N.: Reaction of unimolecular dissociation of formyl radical, HCO → H + CO, studied over 1 - 100 bar buffer gas pressure range. Chemical and Physical Processes in Combustion 1999, 293-295.

(49) Krishtopa, L. G.; Krasnoperov, L. N.: NOx destruction in air and nitrogen by dielectric barrier corona discharge. Society of Automotive Engineers, [Special Publication] SP 1998, SP-1395, 67-72.

(50) Levy, R. A.; Ravindranath, C.; Krasnoperov, L. N.; Opyrchal, J.; Ramos, E. S.: Porous Vycor membranes modified by chemical vapor deposition of boron nitride for gas separation. Journal of the Electrochemical Society 1997, 144, 349-353.

(51) Krishtopa, L. G.; Krasnoperov, L. N.: NOx destruction in air and nitrogen streams by dielectric barrier corona discharge. Preprints - American Chemical Society, Division of Petroleum Chemistry 1997, 42, 823-824.

(52) Krasnoperov, L. N.; Krishtopa, L. G.; Bozzelli, J. W.: Study of volatile organic compounds destruction by dielectric barrier corona discharge. Journal of Advanced Oxidation Technologies 1997, 2, 248-256.

(53) Krasnoperov, L. N.; Kalinovski, I. J.; Niiranen, J. T.; Gutman, D.: Kinetics and Thermochemistry of SiH3 + NO and SiD3 + NO Reactions: Pressure Falloff and SiH3-NO Bond Energy. Journal of Physical Chemistry A 1997, 101, 4929-4938.

(54) Levy, R. A.; Ramos, E. S.; Krasnoperov, L. N.; Datta, A.; Grow, J. M.: Microporous SiO2/Vycor membranes for gas separation. Journal of Materials Research 1996, 11, 3164-3173.

(55) Lay, T. H.; Krasnoperov, L. N.; Venanzi, C. A.; Bozzelli, J. W.; Shokhirev, N. V.: Ab Initio Study of α-Chlorinated Ethyl Hydroperoxides CH3CH2OOH, CH3CHClOOH, and CH3CCl2OOH: Conformational Analysis, Internal Rotation Barriers, Vibrational Frequencies, and Thermodynamic Properties. Journal of Physical Chemistry 1996, 100, 8240-9.

(56) Reitan, B.; Ho, W.; Shi, J.; Pettigrew, C. A.; Krasnoperov, L. N.; Booty, M. R.; Bozzelli, J. W.: Pyrolysis and oxidation of cellulose and styrene: An experimental study of reaction products. Chemical and Physical Processes in Combustion 1995, 387-90.

(57) Krasnoperov, L. N.; Niiranen, J. T.; Gutman, D.; Melius, C. F.; Allendorf, M. D.: Kinetics and thermochemistry of Si(CH3)3 + NO reaction: direct determination of a Si-N bond energy. Journal of Physical Chemistry 1995, 99, 14347-58.

(58) Krasnoperov, L. N.; Niiranen, J. T.; Gutman, D.; Melius, C. F.; Allendorf, M. D.: Kinetics and Thermochemistry of Si(CH3)3 + NO Reaction: Direct Determination of a Si-N Bond Energy. Journal of Physical Chemistry 1994, 98, 9551-7.

(59) Kalinovski, I. J.; Gutman, D.; Krasnoperov, L. N.; Goumri, A.; Yuan, W. J.; Marshall, P.: Kinetics and Thermochemistry of the Reaction Si(CH3)3 + HBr .dblharw. Si(CH3) 3H + Br. Determination of the (CH3)3Si-H Bond Energy. Journal of Physical Chemistry 1994, 98, 9551-7.

(60) Mashnin, T. S.; Chernyshev, A. V.; Krasnoperov, L. N.: Laser photolysis of iodine monochloride. A time-resolved laser magnetic resonance (LMR) measurement of chlorine atom(2P1/2) relative yield. Chemical Physics Letters 1993, 207, 105-9.

(61) Krasnoperov, L. N.; Kalinovski, I. J.; Chu, H. N.; Gutman, D.: Heterogeneous reactions of hydrogen atoms and methyl radicals with a diamond surface in the 300-1133 K temperature range. Journal of Physical Chemistry 1993, 97, 11787-96.

(62) Seakins, P. W.; Pilling, M. J.; Niiranen, J. T.; Gutman, D.; Krasnoperov, L. N.: Kinetics and thermochemistry of R + hydrogen bromide ↹ RH + bromine atom reactions: determinations of the heat of formation of ethyl, isopropyl, sec-butyl and tert-butyl radicals. Journal of Physical Chemistry 1992, 96, 9847-55.

(63) Niiranen, J. T.; Gutman, D.; Krasnoperov, L. N.: Kinetics and thermochemistry of the acetyl radical: study of the acetyl + hydrogen bromide → acetaldehyde + bromine atom reaction. Journal of Physical Chemistry 1992, 96, 5881-6.

(64) Feng, Y.; Niiranen, J.; Krasnoperov, L. N.; Gutman, D.: Fundamental studies of gas/surface processes occurring during methane coupling on 1% strontium/lanthanum oxide (La2O3). Preprints - American Chemical Society, Division of Petroleum Chemistry 1992, 37, 161-6.

(65) Chichinin, A. I.; Krasnoperov, L. N.: Vibrational relaxation of oxygen fluoride (FO) (v = 1) radicals studied by fast-magnetic-field-jump time-resolved LMR. Experiment and theory. Chemical Physics 1990, 143, 281-96.

(66) Chasovnikov, S. A.; Krasnoperov, L. N.: Calculation of the transition region from the pressure for the silane + oxygen reaction. Comparison with an experiment. Kinetika i Kataliz 1990, 31, 1287-92.

(67) Chasovnikov, S. A.; Chernyshev, A. V.; Krasnoperov, L. N.: Pressure quenching of chain branching reactions of silane and silane-d4 chlorination. Chemical Physics 1990, 143, 339-46.

(68) Chichinin, A. I.; Krasnoperov, L. N.: Atomic chlorine(2P1/2) relaxation studied by fast magnetic field jump time-resolved laser magnetic resonance. Chemical Physics Letters 1989, 160, 448-50.

(69) Krasnoperov, L. N.; Nosov, V. V.; Baklanov, A. V.; Panfilov, V. N.: Laser magnetic resonance recording of silyl radicals during thermal decomposition of silane. Khimicheskaya Fizika 1988, 7, 528-38.

(70) Chichin, A. I.; Krasnoperov, L. N.: Laser magnetic resonance registration of trifluorosilyl radical in the gas phase. Khimicheskaya Fizika 1988, 7, 223-7.

(71) Chichinin, A. I.; Krasnoperov, L. N.: Laser magnetic resonance study of steady- state inversion at transitions of fine structure of chlorine atoms in a discharge of constant current and in a high-frequency discharge in an iodine chloride-argon mixture. Khimicheskaya Fizika 1987, 6, 410-11.

(72) Chichinin, A. I.; Chasovnikov, S. A.; Krasnoperov, L. N.: Time-resolution laser magnetic resonance study of relaxation and reaction of chlorine 2P1/2, 2P3/2 atoms with iodine chloride (ICl). Khimicheskaya Fizika 1987, 6, 281-2.

(73) Chichinin, A. I.; Chasovnikov, S. A.; Krasnoperov, L. N.: The laser photolysis of iodine chloride (ICl) at 530 nm: a time-resolved LMR study. Chemical Physics Letters 1987, 138, 371-6. (74) Chasovnikov, S. A.; Krasnoperov, L. N.: Determination of the rate constant of the reaction of the silyl radical with oxygen and nitrosyl chloride by laser-photolysis-laser-magnetic resonance with time resolution. Khimicheskaya Fizika 1987, 6, 956-9.

(75) Chasovnikov, S. A.; Chichinin, A. I.; Krasnoperov, L. N.: Study of the reactivity of chlorine atoms in the 2P3/2 and 2P1/2 states with nitrosyl chloride molecules by time- resolution laser magnetic resonance. Khimicheskaya Fizika 1987, 6, 447-54.

(76) Chasovnikov, S. A.; Chichinin, A. I.; Krasnoperov, L. N.: Time-resolved LMR study on the reactions of chlorine atoms in the ground (2P3/2) and excited (2P1/2) spin-orbital states with nitrosyl chloride. Chemical Physics 1987, 116, 91-9.

(77) Chichinin, A. I.; Krasnoperov, L. N.: Collisional quenching of atomic chlorine (2P1/2) studied by fast magnetic field jump time-resolved laser magnetic resonance. Chemical Physics Letters 1986, 124, 8-13.

(78) Chasovnikov, S. A.; Krasnoperov, L. N.: Direct determination of branching probability per chain unit in the reaction of silane with molecular chlorine by pulsed photolysis time-resolved laser magnetic resonance. Chemical Physics Letters 1986, 124, 248-55.

(79) Bokun, V. C.; Gordon, E. B.; Krasnoperov, L. N.; Sotnichenko, S. A.; Chichinin, A. I.: Photodissociation laser due to the fine-structure 2P1/2 → 2P3/2 electronic transition in a chlorine atom. Kvantovaya Elektronika (Moscow) 1986, 13, 1319-20.

(80) Lavrik, N. L.; Grishin, I. A.; Krasnoperov, L. N.; Molin, I. N.: Optically detected ESR spectra of aromatic anion-radical pairs in exciplex system pyrene-diethylaniline in methanol. Doklady Akademii Nauk SSSR 1985, 283, 667-70 [Phys Chem ].

(81) Demin, V. N.; Krasnoperov, L. N.; Kuznetsov, F. A.: Possible use of an alternating electric current in electroliquid-phase epitaxy. Zhurnal Tekhnicheskoi Fiziki 1985, 55, 2179-83.

(82) Chichinin, A. I.; Krasnoperov, L. N.: Vibrational relaxation of amidogen (ND2) (0,1,0) radicals studied by fast magnetic-field-jump time-resolved LMR. Chemical Physics Letters 1985, 115, 343-8.

(83) Chapovskii, P. L.; Krasnoperov, L. N.; Panfilov, V. N.; Strunin, V. P.: Studies on separation and conversion of spin modifications of methyl fluoride molecules. Chemical Physics 1985, 97, 449-55.

(84) Braun, V. R.; Chichin, A. I.; Krasnoperov, L. N.: Overestimation of the rate constant of the reaction of Cl + SiH4 determined under jet conditions accounting for heterogeneous processes. Kinetika i Kataliz 1985, 26, 449-52.

(85) Krasnoperov, L. N.; Panfilov, V. N.; Strunin, V. P.; Chapovskii, P. L.: Separation of the ortho and para modifications of the fluoromethane molecule by the light-induced drift method. Pis´ma v Zhurnal Eksperimental´noi i Teoreticheskoi Fiziki 1984, 39, 122-4.

(86) Krasnoperov, L. N.; Chesnokov, E. N.; Panfilov, V. N.: The time-resolved LMR method as used to measure elementary reaction rates of chlorine atoms and silyl radicals in pulse photolysis of sulfur chloride (S2Cl2) in the presence of silane. Chemical Physics 1984, 89, 297- 305.

(87) Krasnoperov, L. N.; Chesnokov, E. N.; Panfilov, V. N.: Use of time-resolved LMR for the measurement of rates of elementary atomic chlorine-silyl radical reactions during pulse photolysis of sulfur chloride (S2Cl2) in the presence of silane. Doklady Akademii Nauk SSSR 1984, 277, 625-30 [Phys Chem ]. (88) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Branching chain reactions of silane oxidation and chlorination studied by the laser magnetic resonance technique. Oxidation Communications 1984, 6, 259-71.

(89) Braun, V. R.; Chichinin, A. I.; Krasnoperov, L. N.; Panfilov, V. N.: Study of the features of the heterogeneous loss of chlorine atoms. Kinetika i Kataliz 1984, 25, 1041-7.

(90) Panfilov, V. N.; Krasnoperov, L. N.: Use of a laser magnetic resonance method for studying active intermediate particles of complex chemical reactions. Khimicheskaya Fizika 1983, 468-77.

(91) Krasnoperov, L. N.; Panfilov, V. N.; Nikonorov, Y. I.: Formation of atomic fluorine during the thermal decomposition of nickel(IV) hexafluoro complexes. Kinetika i Kataliz 1983, 24, 1503-4.

(92) Krasnoperov, L. N.; Panfilov, V. N.; Chesnokov, E. N.: Kinetics and mechanism of the branched chain chlorination of silane. Khimicheskaya Fizika 1983, 1053-6.

(93) Chasovnikov, S. A.; Krasnoperov, L. N.; Panfilov, V. N.: Recording of the fluorooxomethyl radical in the gas phase by a laser magnetic resonance method. Khimicheskaya Fizika 1982, 570-4.

(94) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Observation of reversed Lamb saturation dips in the laser magnetic spectrum of the chlorine atom and precise measurement of the isotopic shift of the 2P1/2 ← 2P3/2 transition. Optika i Spektroskopiya 1982, 52, 719-23.

(95) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Study of a branching chain reaction of silane chlorination by the laser magnetic resonance method. Khimicheskaya Fizika 1982, 758-62.

(96) Krasnoperov, L. N.; Braun, V. R.; Nosov, V. V.; Panfilov, V. N.: Recording of the silyl radical by the laser magnetic resonance method. Kinetika i Kataliz 1981, 22, 1332-5.

(97) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Detection of silyl (SiH3) radicals in a diluted silane flame by laser magnetic resonance. Doklady Akademii Nauk SSSR 1981, 260, 901-3 [Phys Chem ].

(98) Panfilov, V. N.; Strunin, V. P.; Serdyuk, N. K.; Krasnoperov, L. N.; Chesnokov, E. N.: Selective action of continuous carbon dioxide laser radiation on the photobromination of methyl fluoride. Lazer. Sistemy, Novosibirsk 1980, 145-79.

(99) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Characteristics of intracavity laser magnetic resonance spectroscopy. Kvantovaya Elektronika (Moscow) 1980, 7, 1895-905.

(100) Panfilov, V. N.; Krasnoperov, L. N.; Strunin, V. P.: Reactivity of vibrationally excited molecules and isotopically selective processes in the presence of continuous IR-laser radiation. Nelinein. Optika. Tr. 6-i Vavilovsk. Konf., Novosibirsk, 1979, Novosibirsk 1979, 56-60.

(101) Krasnopyorov, L. N.; Chesnokov, E. N.; Panfilov, V. N.: The vibrational activation energy of the reaction of atomic bromine(2P3/2) with monofluoromethane. Chemical Physics 1979, 42, 345-53.

(102) Krasnoperov, L. N.; Panfilov, V. N.: Reactivity of (2P1/2) chlorine atoms toward methyl fluoride. Reaction Kinetics and Catalysis Letters 1979, 10, 191-4.

(103) Krasnoperov, L. N.; Panfilov, V. N.: Inverse population of fine structure levels of a chlorine atom in the photodissociation of iodine chloride by the second harmonic of a neodymium laser. Kinetika i Kataliz 1979, 20, 540.

(104) Krasnoperov, L. N.; Panfilov, V. N.: Role of electron and vibrational energy in the Cl(2P3/2,1/2) + CH3F reaction. Teoreticheskaya i Eksperimental´naya Khimiya 1979, 15, 348-58. (105) Krasnoperov, L. N.; Lavrik, N. L.; Molin, Y. N.: Photochemical reactions of chlorine initiated by argon laser radiation. Khimiya Vysokikh Energii 1978, 12, 262-5.

(106) Krasnoperov, L. N.; Braun, V. R.; Panfilov, V. N.: Determination of chlorine atoms formed in molecular chlorine photodissociation by laser magnetic resonance method. Kinetika i Kataliz 1978, 19, 1610.

(107) Krasnopyorov, L. N.; Panfilov, V. N.: Studies of the reactions of bromine(2P±(sub-3/2)) and bromine(2P±(sub-1/2)) atoms with methyl fluoride. Chemical Physics 1977, 25, 375-80.

(108) Krasnoperov, L. N.; Serdyuk, N. K.; Strunin, V. P.; Panfilov, V. N.: Reactivity of electronically excited bromine(2P1/2) atoms towards monofluoromethane. Reaction Kinetics and Catalysis Letters 1977, 7, 321-6.

(109) Krasnoperov, L. N.; Panfilov, V. N.; Strunin, V. P.: Role of electron and vibrational energies in the bromine + methyl fluoride reaction. Khim. Fiz. Protsessov Goreniya i Vzryva. Kinetika Khim. Reaktsii 1977, 91-4.

(110) Gritsan, V. I.; Krasnoperov, L. N.; Panfilov, V. N.: Effect of carbon dioxide laser radiation on the kinetics of gaseous carbon dioxide decomposition. Doklady Akademii Nauk SSSR 1973, 212, 1368-71 [Phys Chem].

Published Editor Refereed Conference Papers and Proceedings

  • P-7. H.-T. Chern, L.N. Krasnoperov, J.W. Bozzelli. "Experimental and Modeling Studies on Thermal Desorption of Organic Contaminants from Sand and Soils". National Conference of the Academy of Certified Hazardous Materials, Atlantic City, NJ, October 5-6, 1997. Conference Compendium (Editor Reviewed).
  • P-6. L.N. Krasnoperov and L.G. Krishtopa. "Kinetic Study of VOCs and NOx Destruction by Dielectric Barrier Corona Discharge", Environmental Applications of Advanced Oxidation Technologies, Proceedings of the Second International Symposium, San Francisco, Feb. 28-March 2, 1996, Proceedings, Section 5, pp.1-17
  • P-5. L.G. Krishtopa and L.N. Krasnoperov. "Removal of NOx from Air Streams by Corona Discharge", Environmental Applications of Advanced Oxidation Technologies, Proceedings of the Second International Symposium, San Francisco, Feb. 28-March 2, 1996, Proceedings, Section 5, pp.150-161.
  • P-4. Hsien-Tsung Chern, L.N. Krasnoperov and J.W. Bozzelli. "Modeling of Heat Transfer in a Rotary Kiln Thermal Desorber for Removal of Petroleum from Soils", American Chemical Society Meeting, Division of Environmental Chemistry, New Orleans, LA, March 24-29, 1996. Book of Extended Abstracts, pp.
  • P-3. B. Reitan, W. Ho, J. Shi, C.A. Pettigrew, L.N. Krasnoperov, M.R. Booty, J.W. Bozzelli. "Pyrolysis and Oxidation of Cellulose and Styrene: an Experimental Study of Reaction Products". The Eastern States Section of the Combustion Institute, Chemical and Physical Processes in Combustion. Worcester, MA, October 16-18, 1996. Proceedings, p. 387-390.
  •  P-2. L.N. Krasnoperov, L.G. Krishtopa and J.W. Bozzelli. "Study of Volatile Organic Compound Destruction by a Dielectric Barrier Discharge". International Symposium on Environmental Technologies: Plasma Systems. Atlanta, Georgia, October 8-11, 1995. Proceedings, V.2, pp. 583-595.
  • P-1. L.N. Krasnoperov, L.G. Krishtopa and J.W. Bozzelli. "Study of Destruction of Organic Compounds by Corona Discharge". Book of Extended Abstracts, 208th National Chemical Society Meeting, Washington, D.C. 1994, August 21-26, pp.26-29.