Lev N. Krasnoperov

Contact Info

Title: Professor, Chemistry
Email: lev.n.krasnoperov@njit.edu
Office: 358 Tiernan
Phone: 973-596-3592
Dept: Chemistry and Environmental Science
Webpage: http://web.njit.edu/~krasnope/

About Me



Education

  • Doctor of Sciences in Physics and Mathematics (Chemical Physics)
  • Institute of Chemical Physics, Moscow, 1991
  • PhD (Chemical Physics), Institute of Chemical Kinetics and Combustion, Novosibirsk, 1979
  • Diploma, Physics and Applied Mathematics, Novosibirsk University, Novosibirsk, 1972

Website

http://web.njit.edu/~krasnope/

Courses Taught

CHEM 231´01S         PhysicalChemistry 1

CHEM 235´00F         Physical Chemistry 2

CHEM 235A:            Physical Chemistry Laboratory: Kinetics of Ozone Formation by Laser Photolysis -Transient UV Spectroscopy

OPSE 601                 Abstract
CS101E                     Experiment5
                                  Experiment 6
CHEM 534 - Chemical Kinetics and Thermodynamics
CHEM 702 - Advanced Chemical Kinetics (Lecture)
CHEM 658 - Advanced Physical Chemistry - Quantum Chemistry (Lecture)
CHEM 335 - Physical Chemistry 2 (Lecture)
CHEM 235 - Physical Chemistry 2 (Lecture)
CHEM 231 - Physical Chemistry 1 (Lecture)- syllabus
CHEM 301 - Chemical Technology (Laboratory)

At the Catholic University of America, Washington, D.C.:

CHEM 530 - Chemical Thermodynamics (Lecture)
Unimolecular Reactions (Lecture)

At Novosibirsk University:
Chemical Kinetics (graduate course, lecture)
General Physics -  4 semesters´ undergraduate course:
    Mechanics,
    Electricity and Magnetism,
    Quantum mechanics,
    Statistical Thermodynamics.
Chemical Kinetics
Molecular Structure and Spectroscopy (graduate course, lecture)
Molecular structure and spectroscopy (undergraduate course, lecture)
Mass Spectrometry (laboratory)
Kinetic Spectroscopy of Laser Magnetic Resonance (laboratory)
Computer Classes in Physical Chemistry (laboratory)

Participation in the Development of New Courses:

OPSE 601 OPTICAL SCIENCE AND ENGINEERING (NJIT) 09/01/98-12/15/98

The course targets applications of optical  methods in a varietyof fields, such as chemistry, chemical engineering, telecommunications,electrical engineering, etc.
 

CS101E INTRODUCTORY OPTICAL SCIENCE (NJIT) 09/01/98-12/15/98

The main objective is to familiarize students from different disciplines with the optical techniques, applications and capabilities.

CHEM 235A NEW PHYSICAL CHEMISTRY LAB (NJIT) 10/01/98-12/15/98

"Introduction of Laser Photolysis – Transient Spectroscopy Experiments in a Physical Chemistry Lab" – a new physical chemistry lab developed andbuilt under NSF Grant DUE-97 51686.
The lab objectives are to introduce students to elementary chemicalkinetics, ozone formation and the modern techniques in kinetic measurements.

CHEM 702 ADVANCED CHEMICAL KINETICS (NJIT) 1/9/95-30/12/95

Graduate course focusing on the role of media chemical reactions, such as pressure fall-off in gas phase unimolecular reactions and solvent properties in liquid phase reactions, and the current chemical reaction rate theories.
 

UNIMOLECULAR REACTIONS 1/9/92-30/12/92 (CUA, Washington, D.C.)

Graduate course focusing on modern theories and applications of unimolecular reactions.
 

CHEMICAL KINETICS 1/9/90-30/12/90 ( Novosibirsk University):1/9/86-30/12/89

Graduate course focusing on elementary and complex chemical reactionsin the gas and liquid phases.

KINETIC SPECTROSCOPY OF LASER MAGNETIC RESONANCE (Novosibirsk University) 1/1/84-30/5/85

An undergraduate laboratory focusing on application of a modern technique of Time Resolved Laser Magnetic Resonance for measurements of rates ofelementary chemical reactions of atoms and free radicals.
 

COMPUTER CLASSES in Physical Chemistry (Novosibirsk University) 9/1/83-12/30/85

An undergraduate laboratory focusing on using computers for solution of  physical chemistry problems.

Research Interests

  • Chemical kinetics and thermodynamics of gas phase reactions. Thermodynamics of free radicals and strengths of chemical bonds.
  • Kinetics of particle nucleation and growth.
  • Reactions in non-thermal plasmas.
  • Supercritical fluids as process media.
  • Reactions, film deposition and nanoparticle formation from supercritical solutions

Published Refereed Journal Papers

 (1) Wirpsza, L.; Krasnoperov, L.; Mustaev, A.: New quinolone-based thiol-reactive
lanthanide luminescent probes. Journal of Photochemistry and Photobiology, A: Chemistry
2013, 253, 30-37.

(2) Sangwan, M.; Krasnoperov Lev, N.: Kinetics of the Gas Phase Reaction CH3 +
HO2. The Journal of Physical Chemistry A, Just Accepted Manuscript. DOI: 10.1021/
jp4000889. Publication Date (Web): March 4, 2013 2013.

(3) Rissanen, M. P.; Amedro, D.; Krasnoperov, L.; Marshall, P.; Timonen, R. S.: Gas
Phase Kinetics and Equilibrium of Allyl Radical Reactions with NO and NO2. Journal of
Physical Chemistry A 2013, 117, 793-805.

(4) Pillai, S.; Krasnoperov, L.; Mustaev, A.: Simple no-chromatography procedure
for amine-reactive Eu3+ luminescent chelates optimal for bioconjugation. Journal of
Photochemistry and Photobiology, A: Chemistry 2013, 255, 16-23.

(5) Wirpsza, L.; Pillai, S.; Batish, M.; Marras, S.; Krasnoperov, L.; Mustaev, A.:
Highly bright avidin-based affinity probes carrying multiple lanthanide chelates. Journal of
Photochemistry and Photobiology, B: Biology 2012, 116, 22-29.

(6) Sangwan, M.; Krasnoperov, L. N.: Disproportionation Channel of Self-Reaction
of Hydroxyl Radical, OH + OH → H2O + O, Studied by Time-Resolved Oxygen Atom
Trapping. Journal of Physical Chemistry A 2012, 116, 11817-11822.

(7) Sangwan, M.; Chesnokov, E. N.; Krasnoperov, L. N.: Reaction OH + OH Studied
over the 298-834 K Temperature and 1 - 100 bar Pressure Ranges. Journal of Physical
Chemistry A 2012, 116, 6282-6294.

(8) Sangwan, M.; Chesnokov, E. N.; Krasnoperov, L. N.: Reaction CH3 + OH
Studied over the 294-714 K Temperature and 1-100 bar Pressure Ranges. Journal of Physical
Chemistry A 2012, 116, 8661-8670.

(9) Pillai, S.; Wirpsza, L.; Kozlov, M.; Marras, S. A. E.; Krasnoperov, L. N.;
Mustaev, A.: New cross-linking quinoline- and quinolone-based luminescent lanthanide probes
for sensitive labeling. Proceedings of SPIE 2012, 8233, 82331C/1-82331C/12.

(10) Pillai, S.; Kozlov, M.; Marras, S. A. E.; Krasnoperov, L. N.; Mustaev, A.: New
Cross-Linking Quinoline and Quinolone Derivatives for Sensitive Fluorescent Labeling. Journal
of Fluorescence 2012, 22, 1021-1032.

(11) Pillai, S.; Kozlov, M.; Marras, S. A. E.; Krasnoperov, L.; Mustaev, A.: Synthesis
and Characterization of New Cross-linkable Quinolone and Quinoline-based Luminescent
Lanthanide Chelates. J. Progress in Nanotechnology and Nano Materials 2012, 1, 18-24.

(12) Kuznetsov, N. A.; Vorobjev, Y. N.; Krasnoperov, L. N.; Fedorova, O. S.:
Thermodynamics of the multi-stage DNA lesion recognition and repair by formamidopyrimidine-
DNA glycosylase using pyrrolocytosine fluorescence-stopped-flow pre-steady-state kinetics.
Nucleic Acids Research 2012, 40, 7384-7392.

(13) Stepanov, V.; Anglade, V.; Balas Hummers, W. A.; Bezmelnitsyn, A. V.;
Krasnoperov, L. N.: Production and Sensitivity Evaluation of Nanocrystalline RDX-based
Explosive Compositions. Propellants, Explosives, Pyrotechnics 2011, 36, 240-246.

(14) Mustaev, A.; Kozlov, M.; Marras, S.; Krasnoperov, L.; Wirpsza, L.; Pillai, S.:
Fluorophore chelated lanthanide luminescent probes with improved quantum efficiency.
(University of Medicine and Dentistry of New Jersey, USA; New Jersey Institute of
Technology). Application: WO WO, 2011; pp 103pp.

(15) Krasnoperov, L. N.: Branching Ratios in the Hydroxyl Reaction with Propene.
Journal of Physical Chemistry A 2011, 115, 2498-2508.

(16) Krasnoperov, L. N.; Marras, S. A. E.; Kozlov, M.; Wirpsza, L.; Mustaev, A.:
Luminescent probes for ultrasensitive detection of nucleic acids. Bioconjugate Chemistry 2010,
21, 319-327.

(17) Chernov, A. A.; Korobeinichev, O. P.; Modenese, C.; Krishtopa, L. G.;
Krasnoperov, L. N.: Kinetics, products, and mechanism of ethane destruction in corona
discharge: Experiments and simulation. Kinetics and Catalysis 2010, 51, 327-336.

(18) Stepanov, V.; Anglade, V.; Balas, W.; Bezmelnitsyn, A.; Krasnoperov, L. N.:
Processing and characterization of nanocrystalline RDX. International Annual Conference of
ICT 2008, 39th, p54/1-p54/15.

(19) Eskola, A. J.; Timonen, R. S.; Marshall, P.; Chesnokov, E. N.; Krasnoperov, L.
N.: Rate Constants and Hydrogen Isotope Substitution Effects in the CH3 + HCl and CH3 + Cl2
Reactions. Journal of Physical Chemistry A 2008, 112, 7391-7401.

(20) Matsunaga, T.; Chernyshev, A. V.; Chesnokov, E. N.; Krasnoperov, L. N.: In situ
optical monitoring of RDX nanoparticles formation during rapid expansion of supercritical CO2
solutions. Physical Chemistry Chemical Physics 2007, 9, 5249-5259.

(21) Chesnokov, E. N.; Krasnoperov, L. N.: Complete thermodynamically consistent
kinetic model of particle nucleation and growth: numerical study of the applicability of the
classical theory of homogeneous nucleation. Journal of Chemical Physics 2007, 126, 144504/1-
144504/15.

(22) Stepanov, V.; Anglade, V.; Bezmelnitsyn, A.; Krasnoperov, L. N.: Production
and characterization of nanocrystalline explosive RDX. AIChE Annual Meeting, Conference
Proceedings, San Francisco, CA, United States, Nov. 12-17, 2006 2006, 399e/1-399e/6.


(23) Krasnoperov, L. N.; Peng, J.; Marshall, P.: Modified Transition State Theory and
Negative Apparent Activation Energies of Simple Metathesis Reactions: Application to the
Reaction CH3 + HBr → CH4 + Br. Journal of Physical Chemistry A 2006, 110, 3110-3120.

(24) Krasnoperov, L. N.: Role of formyl radical (HCO) in hydrocarbon flames.
Khimicheskaya Fizika 2006, 25, 13-17.

(25) Gao, Y.; Alecu, I. M.; Hsieh, P. C.; Morgan, B. P.; Marshall, P.; Krasnoperov, L.
N.: Thermochemistry Is Not a Lower Bound to the Activation Energy of Endothermic Reactions:
A Kinetic Study of the Gas-Phase Reaction of Atomic Chlorine with Ammonia. Journal of
Physical Chemistry A 2006, 110, 6844-6850.

(26) Stepanov, V.; Samuels, P.; Elkina, I. B.; Zhang, X.; Lavrik, N. L.; Krasnoperov,
L. N.: Recrystallization of RDX by rapid expansion of supercritical solutions (RESS).
International Annual Conference of ICT 2005, 36th, 189/1-189/8.

(27) Stepanov, V.; Krasnoperov, L. N.; Elkina, I. B.; Zhang, X.: Production of
nanocrystalline RDX by Rapid Expansion of Supercritical Solutions. Propellants, Explosives,
Pyrotechnics 2005, 30, 178-183.

(28) Krasnoperov, L. N.; Chesnokov, E. N.; Stark, H.; Ravishankara, A. R.:
Elementary reactions of formyl (HCO) radical studied by laser photolysis-transient absorption
spectroscopy. Proceedings of the Combustion Institute 2005, 30, 935-943.

(29) Krasnoperov, L. N.: The thermal unimolecular decomposition of HCO: effect of
state specific rate constants on the thermal rate constant. Comment. Physical Chemistry
Chemical Physics 2005, 7, 2074-2076.

(30) Johnson, D.; Raoult, S.; Lesclaux, R.; Krasnoperov, L. N.: UV absorption spectra
of methyl-substituted hydroxy-cyclohexadienyl radicals in the gas phase. Journal of
Photochemistry and Photobiology, A: Chemistry 2005, 176, 98-106.

(31) Krasnoperov, L. N.; Michael, J. V.: Shock Tube Studies Using a Novel Multipass
Absorption Cell: Rate Constant Results For OH + H2 and OH + C2H6. Journal of Physical
Chemistry A 2004, 108, 5643-5648.

(32) Krasnoperov, L. N.; Michael, J. V.: High-Temperature Shock Tube Studies Using
Multipass Absorption: Rate Constant Results for OH + CH3, OH + CH2, and the Dissociation of
CH3OH. Journal of Physical Chemistry A 2004, 108, 8317-8323.

(33) Krasnoperov, L. N.; Chesnokov, E. N.; Stark, H.; Ravishankara, A. R.:
Unimolecular Dissociation of Formyl Radical, HCO → H + CO, Studied over 1-100 Bar
Pressure Range. Journal of Physical Chemistry A 2004, 108, 11526-11536.

(34) Hahn, J.; Krasnoperov, L.; Luther, K.; Troe, J.: Pressure dependence of the
reaction H + O2 (+Ar) → HO2 (+Ar) in the range 1-900 bar and 300-700 K. Physical Chemistry
Chemical Physics 2004, 6, 1997-1999.

(35) Grebenkin, S. Y.; Krasnoperov, L. N.: Kinetics and Thermochemistry of the
Hydroxycyclohexadienyl Radical Reaction with O2: C6H6OH + O2 .dblharw. C6H6(OH)OO.
Journal of Physical Chemistry A 2004, 108, 1953-1963.

(36) Krishtopa, L. G.; Krasnoperov, L. N.: Destruction of isotopically enriched nitric
oxide, 15N18O, in air in corona discharge: direct observation of NOx reduction to molecular
nitrogen. Journal of Advanced Oxidation Technologies 2003, 6, 30-34.

(37) Glebov, E. M.; Krishtopa, L. G.; Stepanov, V.; Krasnoperov, L. N.: Reply to
Comment on "Kinetics of a Diels-Alder Reaction of Maleic Anhydride and Isoprene in
Supercritical CO2". Journal of Physical Chemistry A 2003, 107, 9249.

(38) Chernov, A. A.; Krishtopa, L. G.; Korobeinichev, O. P.; Krasnoperov, L. N.:
Kinetics, products and mechanism of destruction of ethane in corona discharge. Journal of
Advanced Oxidation Technologies 2003, 6, 23-29.

(39) Korobeinichev, O. P.; Chernov, A. A.; Sokolov, V. V.; Krasnoperov, L. N.:
Kinetics of destruction of diisopropyl methylphosphonate in corona discharge. International
Journal of Chemical Kinetics 2002, 34, 331-337.

(40) Korobeinichev, O. P.; Chernov, A. A.; Sokolov, V. V.; Krasnoperov, L. N.:
Degradation of organophosphorus compounds in a corona discharge. Khimicheskaya Fizika
2002, 21, 27-31.

(41) Dubtsov, S. N.; Chesnokov, E. N.; Krasnoperov, L. N.: Kinetics of the aerosol
formation at 193-nm photolysis of 1,4-cyclohexadiene-NO-air mixture. Atmospheric and
Oceanic Optics 2002, 15, 445-447.

(42) Glebov, E. M.; Yuan, L.; Krishtopa, L. G.; Usov, O. M.; Krasnoperov, L. N.:
Coating of Metal Powders with Polymers in Supercritical Carbon Dioxide. Industrial &
Engineering Chemistry Research 2001, 40, 4058-4068.

(43) Glebov, E. M.; Krishtopa, L. G.; Stepanov, V.; Krasnoperov, L. N.: Kinetics of a
Diels-Alder Reaction of Maleic Anhydride and Isoprene in Supercritical CO2. Journal of
Physical Chemistry A 2001, 105, 9427-9435.

(44) Baklanov, A. V.; Krasnoperov, L. N.: Oxalyl Chloride-A Clean Source of
Chlorine Atoms for Kinetic Studies. Journal of Physical Chemistry A 2001, 105, 97-103.

(45) Baklanov, A. V.; Krasnoperov, L. N.: UV Absorption Spectrum and Rate
Constant for Self-Reaction of Silyl Radicals. Journal of Physical Chemistry A 2001, 105, 4917-
4922.

(46) Krasnoperov, L. N.; Stepanov, V.: Introduction of laser photolysis-transient
spectroscopy in an undergraduate physical chemistry laboratory: kinetics of ozone formation.
Journal of Chemical Education 1999, 76, 1182-1183.

(47) Krasnoperov, L. N.; Mehta, K.: Kinetic Study of CH3 + HBr and CH3 + Br
Reactions by Laser Photolysis-Transient Absorption over 1-100 Bar Pressure Range. Journal of
Physical Chemistry A 1999, 103, 8008-8020.

(48) Krasnoperov, L. N.; Chesnokov, E. N.: Reaction of unimolecular dissociation of
formyl radical, HCO → H + CO, studied over 1 - 100 bar buffer gas pressure range. Chemical
and Physical Processes in Combustion 1999, 293-295.

(49) Krishtopa, L. G.; Krasnoperov, L. N.: NOx destruction in air and nitrogen by
dielectric barrier corona discharge. Society of Automotive Engineers, [Special Publication] SP
1998, SP-1395, 67-72.

(50) Levy, R. A.; Ravindranath, C.; Krasnoperov, L. N.; Opyrchal, J.; Ramos, E. S.:
Porous Vycor membranes modified by chemical vapor deposition of boron nitride for gas
separation. Journal of the Electrochemical Society 1997, 144, 349-353.

(51) Krishtopa, L. G.; Krasnoperov, L. N.: NOx destruction in air and nitrogen streams
by dielectric barrier corona discharge. Preprints - American Chemical Society, Division of
Petroleum Chemistry 1997, 42, 823-824.

(52) Krasnoperov, L. N.; Krishtopa, L. G.; Bozzelli, J. W.: Study of volatile organic
compounds destruction by dielectric barrier corona discharge. Journal of Advanced Oxidation
Technologies 1997, 2, 248-256.

(53) Krasnoperov, L. N.; Kalinovski, I. J.; Niiranen, J. T.; Gutman, D.: Kinetics and
Thermochemistry of SiH3 + NO and SiD3 + NO Reactions: Pressure Falloff and SiH3-NO Bond
Energy. Journal of Physical Chemistry A 1997, 101, 4929-4938.

(54) Levy, R. A.; Ramos, E. S.; Krasnoperov, L. N.; Datta, A.; Grow, J. M.:
Microporous SiO2/Vycor membranes for gas separation. Journal of Materials Research 1996,
11, 3164-3173.

(55) Lay, T. H.; Krasnoperov, L. N.; Venanzi, C. A.; Bozzelli, J. W.; Shokhirev, N.
V.: Ab Initio Study of α-Chlorinated Ethyl Hydroperoxides CH3CH2OOH, CH3CHClOOH, and
CH3CCl2OOH: Conformational Analysis, Internal Rotation Barriers, Vibrational Frequencies,
and Thermodynamic Properties. Journal of Physical Chemistry 1996, 100, 8240-9.

(56) Reitan, B.; Ho, W.; Shi, J.; Pettigrew, C. A.; Krasnoperov, L. N.; Booty, M. R.;
Bozzelli, J. W.: Pyrolysis and oxidation of cellulose and styrene: An experimental study of
reaction products. Chemical and Physical Processes in Combustion 1995, 387-90.

(57) Krasnoperov, L. N.; Niiranen, J. T.; Gutman, D.; Melius, C. F.; Allendorf, M. D.:
Kinetics and thermochemistry of Si(CH3)3 + NO reaction: direct determination of a Si-N bond
energy. Journal of Physical Chemistry 1995, 99, 14347-58.

(58) Krasnoperov, L. N.; Niiranen, J. T.; Gutman, D.; Melius, C. F.; Allendorf, M. D.:
Kinetics and Thermochemistry of Si(CH3)3 + NO Reaction: Direct Determination of a Si-N
Bond Energy. Journal of Physical Chemistry 1994, 98, 9551-7.

(59) Kalinovski, I. J.; Gutman, D.; Krasnoperov, L. N.; Goumri, A.; Yuan, W. J.;
Marshall, P.: Kinetics and Thermochemistry of the Reaction Si(CH3)3 + HBr .dblharw. Si(CH3)
3H + Br. Determination of the (CH3)3Si-H Bond Energy. Journal of Physical Chemistry 1994, 98, 9551-7.

(60) Mashnin, T. S.; Chernyshev, A. V.; Krasnoperov, L. N.: Laser photolysis of
iodine monochloride. A time-resolved laser magnetic resonance (LMR) measurement of chlorine
atom(2P1/2) relative yield. Chemical Physics Letters 1993, 207, 105-9.

(61) Krasnoperov, L. N.; Kalinovski, I. J.; Chu, H. N.; Gutman, D.: Heterogeneous
reactions of hydrogen atoms and methyl radicals with a diamond surface in the 300-1133 K
temperature range. Journal of Physical Chemistry 1993, 97, 11787-96.

(62) Seakins, P. W.; Pilling, M. J.; Niiranen, J. T.; Gutman, D.; Krasnoperov, L. N.:
Kinetics and thermochemistry of R + hydrogen bromide ↹ RH + bromine atom reactions:
determinations of the heat of formation of ethyl, isopropyl, sec-butyl and tert-butyl radicals.
Journal of Physical Chemistry 1992, 96, 9847-55.

(63) Niiranen, J. T.; Gutman, D.; Krasnoperov, L. N.: Kinetics and thermochemistry of
the acetyl radical: study of the acetyl + hydrogen bromide → acetaldehyde + bromine atom
reaction. Journal of Physical Chemistry 1992, 96, 5881-6.

(64) Feng, Y.; Niiranen, J.; Krasnoperov, L. N.; Gutman, D.: Fundamental studies of
gas/surface processes occurring during methane coupling on 1% strontium/lanthanum oxide
(La2O3). Preprints - American Chemical Society, Division of Petroleum Chemistry 1992, 37,
161-6.

(65) Chichinin, A. I.; Krasnoperov, L. N.: Vibrational relaxation of oxygen fluoride
(FO) (v = 1) radicals studied by fast-magnetic-field-jump time-resolved LMR. Experiment and
theory. Chemical Physics 1990, 143, 281-96.

(66) Chasovnikov, S. A.; Krasnoperov, L. N.: Calculation of the transition region from
the pressure for the silane + oxygen reaction. Comparison with an experiment. Kinetika i Kataliz
1990, 31, 1287-92.

(67) Chasovnikov, S. A.; Chernyshev, A. V.; Krasnoperov, L. N.: Pressure quenching
of chain branching reactions of silane and silane-d4 chlorination. Chemical Physics 1990, 143,
339-46.

(68) Chichinin, A. I.; Krasnoperov, L. N.: Atomic chlorine(2P1/2) relaxation studied
by fast magnetic field jump time-resolved laser magnetic resonance. Chemical Physics Letters
1989, 160, 448-50.

(69) Krasnoperov, L. N.; Nosov, V. V.; Baklanov, A. V.; Panfilov, V. N.: Laser
magnetic resonance recording of silyl radicals during thermal decomposition of silane.
Khimicheskaya Fizika 1988, 7, 528-38.

(70) Chichin, A. I.; Krasnoperov, L. N.: Laser magnetic resonance registration of
trifluorosilyl radical in the gas phase. Khimicheskaya Fizika 1988, 7, 223-7.

(71) Chichinin, A. I.; Krasnoperov, L. N.: Laser magnetic resonance study of steady-
state inversion at transitions of fine structure of chlorine atoms in a discharge of constant current
and in a high-frequency discharge in an iodine chloride-argon mixture. Khimicheskaya Fizika
1987, 6, 410-11.

(72) Chichinin, A. I.; Chasovnikov, S. A.; Krasnoperov, L. N.: Time-resolution laser
magnetic resonance study of relaxation and reaction of chlorine 2P1/2, 2P3/2 atoms with iodine
chloride (ICl). Khimicheskaya Fizika 1987, 6, 281-2.

(73) Chichinin, A. I.; Chasovnikov, S. A.; Krasnoperov, L. N.: The laser photolysis of
iodine chloride (ICl) at 530 nm: a time-resolved LMR study. Chemical Physics Letters 1987,
138, 371-6.

(74) Chasovnikov, S. A.; Krasnoperov, L. N.: Determination of the rate constant of the
reaction of the silyl radical with oxygen and nitrosyl chloride by laser-photolysis-laser-magnetic
resonance with time resolution. Khimicheskaya Fizika 1987, 6, 956-9.

(75) Chasovnikov, S. A.; Chichinin, A. I.; Krasnoperov, L. N.: Study of the reactivity
of chlorine atoms in the 2P3/2 and 2P1/2 states with nitrosyl chloride molecules by time-
resolution laser magnetic resonance. Khimicheskaya Fizika 1987, 6, 447-54.

(76) Chasovnikov, S. A.; Chichinin, A. I.; Krasnoperov, L. N.: Time-resolved LMR
study on the reactions of chlorine atoms in the ground (2P3/2) and excited (2P1/2) spin-orbital
states with nitrosyl chloride. Chemical Physics 1987, 116, 91-9.

(77) Chichinin, A. I.; Krasnoperov, L. N.: Collisional quenching of atomic chlorine
(2P1/2) studied by fast magnetic field jump time-resolved laser magnetic resonance. Chemical
Physics Letters 1986, 124, 8-13.

(78) Chasovnikov, S. A.; Krasnoperov, L. N.: Direct determination of branching
probability per chain unit in the reaction of silane with molecular chlorine by pulsed photolysis
time-resolved laser magnetic resonance. Chemical Physics Letters 1986, 124, 248-55.

(79) Bokun, V. C.; Gordon, E. B.; Krasnoperov, L. N.; Sotnichenko, S. A.; Chichinin,
A. I.: Photodissociation laser due to the fine-structure 2P1/2 → 2P3/2 electronic transition in a
chlorine atom. Kvantovaya Elektronika (Moscow) 1986, 13, 1319-20.

(80) Lavrik, N. L.; Grishin, I. A.; Krasnoperov, L. N.; Molin, I. N.: Optically detected
ESR spectra of aromatic anion-radical pairs in exciplex system pyrene-diethylaniline in
methanol. Doklady Akademii Nauk SSSR 1985, 283, 667-70 [Phys Chem ].

(81) Demin, V. N.; Krasnoperov, L. N.; Kuznetsov, F. A.: Possible use of an
alternating electric current in electroliquid-phase epitaxy. Zhurnal Tekhnicheskoi Fiziki 1985, 55,
2179-83.

(82) Chichinin, A. I.; Krasnoperov, L. N.: Vibrational relaxation of amidogen (ND2)
(0,1,0) radicals studied by fast magnetic-field-jump time-resolved LMR. Chemical Physics
Letters 1985, 115, 343-8.

(83) Chapovskii, P. L.; Krasnoperov, L. N.; Panfilov, V. N.; Strunin, V. P.: Studies on
separation and conversion of spin modifications of methyl fluoride molecules. Chemical Physics
1985, 97, 449-55.

(84) Braun, V. R.; Chichin, A. I.; Krasnoperov, L. N.: Overestimation of the rate
constant of the reaction of Cl + SiH4 determined under jet conditions accounting for
heterogeneous processes. Kinetika i Kataliz 1985, 26, 449-52.

(85) Krasnoperov, L. N.; Panfilov, V. N.; Strunin, V. P.; Chapovskii, P. L.: Separation
of the ortho and para modifications of the fluoromethane molecule by the light-induced drift
method. Pis´ma v Zhurnal Eksperimental´noi i Teoreticheskoi Fiziki 1984, 39, 122-4.

(86) Krasnoperov, L. N.; Chesnokov, E. N.; Panfilov, V. N.: The time-resolved LMR
method as used to measure elementary reaction rates of chlorine atoms and silyl radicals in pulse
photolysis of sulfur chloride (S2Cl2) in the presence of silane. Chemical Physics 1984, 89, 297-
305.

(87) Krasnoperov, L. N.; Chesnokov, E. N.; Panfilov, V. N.: Use of time-resolved
LMR for the measurement of rates of elementary atomic chlorine-silyl radical reactions during
pulse photolysis of sulfur chloride (S2Cl2) in the presence of silane. Doklady Akademii Nauk
SSSR 1984, 277, 625-30 [Phys Chem ].

(88) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Branching chain reactions of
silane oxidation and chlorination studied by the laser magnetic resonance technique. Oxidation
Communications 1984, 6, 259-71.

(89) Braun, V. R.; Chichinin, A. I.; Krasnoperov, L. N.; Panfilov, V. N.: Study of the
features of the heterogeneous loss of chlorine atoms. Kinetika i Kataliz 1984, 25, 1041-7.

(90) Panfilov, V. N.; Krasnoperov, L. N.: Use of a laser magnetic resonance method
for studying active intermediate particles of complex chemical reactions. Khimicheskaya Fizika
1983, 468-77.

(91) Krasnoperov, L. N.; Panfilov, V. N.; Nikonorov, Y. I.: Formation of atomic
fluorine during the thermal decomposition of nickel(IV) hexafluoro complexes. Kinetika i
Kataliz 1983, 24, 1503-4.

(92) Krasnoperov, L. N.; Panfilov, V. N.; Chesnokov, E. N.: Kinetics and mechanism
of the branched chain chlorination of silane. Khimicheskaya Fizika 1983, 1053-6.

(93) Chasovnikov, S. A.; Krasnoperov, L. N.; Panfilov, V. N.: Recording of the
fluorooxomethyl radical in the gas phase by a laser magnetic resonance method. Khimicheskaya
Fizika 1982, 570-4.

(94) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Observation of reversed Lamb
saturation dips in the laser magnetic spectrum of the chlorine atom and precise measurement of
the isotopic shift of the 2P1/2 ← 2P3/2 transition. Optika i Spektroskopiya 1982, 52, 719-23.

(95) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Study of a branching chain
reaction of silane chlorination by the laser magnetic resonance method. Khimicheskaya Fizika
1982, 758-62.

(96) Krasnoperov, L. N.; Braun, V. R.; Nosov, V. V.; Panfilov, V. N.: Recording of
the silyl radical by the laser magnetic resonance method. Kinetika i Kataliz 1981, 22, 1332-5.

(97) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Detection of silyl (SiH3)
radicals in a diluted silane flame by laser magnetic resonance. Doklady Akademii Nauk SSSR
1981, 260, 901-3 [Phys Chem ].

(98) Panfilov, V. N.; Strunin, V. P.; Serdyuk, N. K.; Krasnoperov, L. N.; Chesnokov,
E. N.: Selective action of continuous carbon dioxide laser radiation on the photobromination of
methyl fluoride. Lazer. Sistemy, Novosibirsk 1980, 145-79.

(99) Braun, V. R.; Krasnoperov, L. N.; Panfilov, V. N.: Characteristics of intracavity
laser magnetic resonance spectroscopy. Kvantovaya Elektronika (Moscow) 1980, 7, 1895-905.

(100) Panfilov, V. N.; Krasnoperov, L. N.; Strunin, V. P.: Reactivity of vibrationally
excited molecules and isotopically selective processes in the presence of continuous IR-laser
radiation. Nelinein. Optika. Tr. 6-i Vavilovsk. Konf., Novosibirsk, 1979, Novosibirsk 1979, 56-60.

(101) Krasnopyorov, L. N.; Chesnokov, E. N.; Panfilov, V. N.: The vibrational
activation energy of the reaction of atomic bromine(2P3/2) with monofluoromethane. Chemical
Physics 1979, 42, 345-53.

(102) Krasnoperov, L. N.; Panfilov, V. N.: Reactivity of (2P1/2) chlorine atoms toward
methyl fluoride. Reaction Kinetics and Catalysis Letters 1979, 10, 191-4.

(103) Krasnoperov, L. N.; Panfilov, V. N.: Inverse population of fine structure levels of
a chlorine atom in the photodissociation of iodine chloride by the second harmonic of a
neodymium laser. Kinetika i Kataliz 1979, 20, 540.

(104) Krasnoperov, L. N.; Panfilov, V. N.: Role of electron and vibrational energy in
the Cl(2P3/2,1/2) + CH3F reaction. Teoreticheskaya i Eksperimental´naya Khimiya 1979, 15,
348-58.

(105) Krasnoperov, L. N.; Lavrik, N. L.; Molin, Y. N.: Photochemical reactions of
chlorine initiated by argon laser radiation. Khimiya Vysokikh Energii 1978, 12, 262-5.

(106) Krasnoperov, L. N.; Braun, V. R.; Panfilov, V. N.: Determination of chlorine
atoms formed in molecular chlorine photodissociation by laser magnetic resonance method.
Kinetika i Kataliz 1978, 19, 1610.

(107) Krasnopyorov, L. N.; Panfilov, V. N.: Studies of the reactions of
bromine(2P±(sub-3/2)) and bromine(2P±(sub-1/2)) atoms with methyl fluoride. Chemical
Physics 1977, 25, 375-80.

(108) Krasnoperov, L. N.; Serdyuk, N. K.; Strunin, V. P.; Panfilov, V. N.: Reactivity of
electronically excited bromine(2P1/2) atoms towards monofluoromethane. Reaction Kinetics and
Catalysis Letters 1977, 7, 321-6.

(109) Krasnoperov, L. N.; Panfilov, V. N.; Strunin, V. P.: Role of electron and
vibrational energies in the bromine + methyl fluoride reaction. Khim. Fiz. Protsessov Goreniya i
Vzryva. Kinetika Khim. Reaktsii 1977, 91-4.

(110) Gritsan, V. I.; Krasnoperov, L. N.; Panfilov, V. N.: Effect of carbon dioxide laser
radiation on the kinetics of gaseous carbon dioxide decomposition. Doklady Akademii Nauk
SSSR 1973, 212, 1368-71 [Phys Chem].

Published Editor Refereed Conference Papers and Proceedings

  • P-7. H.-T. Chern, L.N. Krasnoperov, J.W. Bozzelli. "Experimental and Modeling Studies on Thermal Desorption of Organic Contaminants from Sand and Soils". National Conference of the Academy of Certified Hazardous Materials, Atlantic City, NJ, October 5-6, 1997. Conference Compendium (Editor Reviewed).
  • P-6. L.N. Krasnoperov and L.G. Krishtopa. "Kinetic Study of VOCs and NOx Destruction by Dielectric Barrier Corona Discharge", Environmental Applications of Advanced Oxidation Technologies, Proceedings of the Second International Symposium, San Francisco, Feb. 28-March 2, 1996, Proceedings, Section 5, pp.1-17
  • P-5. L.G. Krishtopa and L.N. Krasnoperov. "Removal of NOx from Air Streams by Corona Discharge", Environmental Applications of Advanced Oxidation Technologies, Proceedings of the Second International Symposium, San Francisco, Feb. 28-March 2, 1996, Proceedings, Section 5, pp.150-161.
  • P-4. Hsien-Tsung Chern, L.N. Krasnoperov and J.W. Bozzelli. "Modeling of Heat Transfer in a Rotary Kiln Thermal Desorber for Removal of Petroleum from Soils", American Chemical Society Meeting, Division of Environmental Chemistry, New Orleans, LA, March 24-29, 1996. Book of Extended Abstracts, pp.
  • P-3. B. Reitan, W. Ho, J. Shi, C.A. Pettigrew, L.N. Krasnoperov, M.R. Booty, J.W. Bozzelli. "Pyrolysis and Oxidation of Cellulose and Styrene: an Experimental Study of Reaction Products". The Eastern States Section of the Combustion Institute, Chemical and Physical Processes in Combustion. Worcester, MA, October 16-18, 1996. Proceedings, p. 387-390.
  •  P-2. L.N. Krasnoperov, L.G. Krishtopa and J.W. Bozzelli. "Study of Volatile Organic Compound Destruction by a Dielectric Barrier Discharge". International Symposium on Environmental Technologies: Plasma Systems. Atlanta, Georgia, October 8-11, 1995. Proceedings, V.2, pp. 583-595.
  • P-1. L.N. Krasnoperov, L.G. Krishtopa and J.W. Bozzelli. "Study of Destruction of Organic Compounds by Corona Discharge". Book of Extended Abstracts, 208th National Chemical Society Meeting, Washington, D.C. 1994, August 21-26, pp.26-29.